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Cyanide Complexes Based on {Mo(6)I(8)}(4+) and {W(6)I(8)}(4+) Cluster Cores

Compounds based on new cyanide cluster anions [{Mo(6)I(8)}(CN)(6)](2–), trans-[{Mo(6)I(8)}(CN)(4)(MeO)(2)](2–) and trans-[{W(6)I(8)}(CN)(2)(MeO)(4)](2−) were synthesized using mechanochemical or solvothermal synthesis. The crystal and electronic structures as well as spectroscopic properties of the...

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Detalles Bibliográficos
Autores principales: Pronin, Aleksei S., Yarovoy, Spartak S., Gayfulin, Yakov M., Ryadun, Aleksey A., Brylev, Konstantin A., Samsonenko, Denis G., Eltsov, Ilia V., Mironov, Yuri V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7764029/
https://www.ncbi.nlm.nih.gov/pubmed/33302595
http://dx.doi.org/10.3390/molecules25245796