Cargando…

Bis-silylation of internal alkynes enabled by Ni(0) catalysis

1,2-Bis-silyl alkenes have exciting synthetic potential for programmable sequential synthesis via manipulation of the two vicinal silyl groups. Transition metal-catalyzed bis-silylation of alkynes with disilanes is the most straightforward strategy to access such useful building blocks. However, thi...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Yun, Wang, Xi-Chao, Ju, Cheng-Wei, Zhao, Dongbing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7782505/
https://www.ncbi.nlm.nih.gov/pubmed/33397974
http://dx.doi.org/10.1038/s41467-020-20392-w