Counterion-Enhanced Pd/Enamine Catalysis: Direct Asymmetric α-Allylation of Aldehydes with Allylic Alcohols by Chiral Amines and Achiral or Racemic Phosphoric Acids

[Image: see text] We report a straightforward and efficient Pd/enamine catalytic procedure for the direct asymmetric α-allylation of branched aldehydes. The use of simple chiral amines and easily prepared achiral or racemic phosphoric acids, together with a suitable Pd-source resulted in a highly ac...

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Detalles Bibliográficos
Autores principales: Pálvölgyi, Ádám Márk, Smith, Jakob, Schnürch, Michael, Bica-Schröder, Katharina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7783732/
https://www.ncbi.nlm.nih.gov/pubmed/33320681
http://dx.doi.org/10.1021/acs.joc.0c02385

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7783732/
https://www.ncbi.nlm.nih.gov/pubmed/33320681
http://dx.doi.org/10.1021/acs.joc.0c02385

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