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Generation of Mixed Anhydrides via Oxidative Fragmentation of Tertiary Cyclopropanols with Phenyliodine(III) Dicarboxylates

Oxidative fragmentation of tertiary cyclopropanols with phenyliodine(III) dicarboxylates in aprotic solvents (dichloromethane, chloroform, toluene) produces mixed anhydrides. The fragmentation reaction is especially facile with phenyliodine(III) reagents bearing electron-withdrawing carboxylate liga...

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Detalles Bibliográficos
Autores principales: Zubrytski, Dzmitry M., Elek, Gábor Zoltán, Lopp, Margus, Kananovich, Dzmitry G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7794720/
https://www.ncbi.nlm.nih.gov/pubmed/33396847
http://dx.doi.org/10.3390/molecules26010140