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When Attempting Chain Extension, Even Without Solvent, It Is Not Possible to Avoid Chojnowski Metathesis Giving D(3)
A simple, mild and efficient method to prepare HSi- or HOSi-telechelic, high-molecular-weight polydimethylsiloxane polymers (to 41,600 g·mol(−1)) using the one-shot hydrolysis of M(H)M(H) is reported; titration of the water allowed for higher molecular weights (to 153,900 g·mol(−1)). The “living” ch...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7795595/ https://www.ncbi.nlm.nih.gov/pubmed/33466286 http://dx.doi.org/10.3390/molecules26010231 |