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On the Heterogeneous Nature of Cisplatin‐1‐Methyluracil Complexes: Coexistence of Different Aggregation Modes and Partial Loss of NH(3) Ligands as Likely Explanation

The conversion of the 1 : 1‐complex of Cisplatin with 1‐methyluracil (1MeUH), cis‐[Pt(NH(3))(2)(1MeU‐N3)Cl] (1 a) to the aqua species cis‐[Pt(NH(3))(2)(1MeU‐N3)(OH(2))](+) (1 b), achieved by reaction of 1 a with AgNO(3) in water, affords a mixture of compounds, the composition of which strongly depe...

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Detalles Bibliográficos
Autores principales: Pullen, Sonja, Hegmans, Alexander, Hiller, Wolf G., Platzek, André, Freisinger, Eva, Lippert, Bernhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7809254/
https://www.ncbi.nlm.nih.gov/pubmed/33448132
http://dx.doi.org/10.1002/open.202000317