Competition between cyclization and unusual Norrish type I and type II nitro-acyl migration pathways in the photouncaging of 1-acyl-7-nitroindoline revealed by computations

The 7-nitroindolinyl family of caging chromophores has received much attention in the past two decades. However, its uncaging mechanism is still not clearly understood. In this study, we performed state-of-the-art density functional theory calculations to unravel the photo-uncaging mechanism in its...

Descripción completa

Detalles Bibliográficos
Autores principales: Morgante, Pierpaolo, Guruge, Charitha, Ouedraogo, Yannick P., Nesnas, Nasri, Peverati, Roberto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7809399/
https://www.ncbi.nlm.nih.gov/pubmed/33446751
http://dx.doi.org/10.1038/s41598-020-79701-4

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7809399/
https://www.ncbi.nlm.nih.gov/pubmed/33446751
http://dx.doi.org/10.1038/s41598-020-79701-4

Ejemplares similares