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Predicting Nitrogen‐Based Families of Compounds: Transition‐Metal Guanidinates TCN(3) (T=V, Nb, Ta) and Ortho‐Nitrido Carbonates T′ (2)CN(4) (T′=Ti, Zr, Hf)
Due to its unsurpassed capability to engage in various sp hybridizations or orbital mixings, carbon may contribute in expanding solid‐state nitrogen chemistry by allowing for different complex anions, such as the known NCN(2−) carbodiimide unit, the so far unknown CN(3) (5−) guanidinate anion, and t...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7821139/ https://www.ncbi.nlm.nih.gov/pubmed/33001558 http://dx.doi.org/10.1002/anie.202011196 |