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Tuning the Proton‐Coupled Electron‐Transfer Rate by Ligand Modification in Catalyst–Dye Supramolecular Complexes for Photocatalytic Water Splitting
In view of the considerably high activation energy barrier of the O−O bond formation photocatalytic step in water oxidation, it is essential to understand if and how nonadiabatic factors can accelerate the proton‐coupled electron transfer (PCET) rate in this process to find rational design strategie...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7821158/ https://www.ncbi.nlm.nih.gov/pubmed/32871047 http://dx.doi.org/10.1002/cssc.202001863 |