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Well‐Defined, Molecular Bismuth Compounds: Catalysts in Photochemically Induced Radical Dehydrocoupling Reactions

A series of diorgano(bismuth)chalcogenides, [Bi(di‐aryl)EPh], has been synthesised and fully characterised (E=S, Se, Te). These molecular bismuth complexes have been exploited in homogeneous photochemically‐induced radical catalysis, using the coupling of silanes with TEMPO as a model reaction (TEMP...

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Detalles Bibliográficos
Autores principales: Ramler, Jacqueline, Krummenacher, Ivo, Lichtenberg, Crispin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7821184/
https://www.ncbi.nlm.nih.gov/pubmed/32573876
http://dx.doi.org/10.1002/chem.202002219