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Attempts to Synthesize a Thiirane, Selenirane, and Thiirene by Dealkylation of Chalcogeniranium and Thiirenium Salts
Thiiranium salts [Ad(2)SR](+)X(−) (5, 8, 9, 11, 12; X(−)=Tf(2)N(−) (Tf=CF(3)SO(2)), SbCl(6) (−)) and seleniranium salts [Ad(2)SeR](+)X(−) (14, 16, 17, 23–25; X(−)=Tf(2)N(−), BF(4) (−), CHB(11)Cl(11) (−), SbCl(6) (−)) are synthesized from strained alkene bis(adamantylidene) (1). The disulfides and th...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7821244/ https://www.ncbi.nlm.nih.gov/pubmed/32737908 http://dx.doi.org/10.1002/chem.202003461 |