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Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization
Rollover cyclometalation constitutes a particular case of cyclometallation reaction. This reaction occurs when a chelated heterocyclic ligand loses its bidentate coordination mode and undergoes an internal rotation, after which a remote C–H bond is regioselectively activated, affording an uncommon c...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7827749/ https://www.ncbi.nlm.nih.gov/pubmed/33435257 http://dx.doi.org/10.3390/molecules26020328 |