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Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization

Rollover cyclometalation constitutes a particular case of cyclometallation reaction. This reaction occurs when a chelated heterocyclic ligand loses its bidentate coordination mode and undergoes an internal rotation, after which a remote C–H bond is regioselectively activated, affording an uncommon c...

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Detalles Bibliográficos
Autores principales:	Zucca, Antonio, Pilo, Maria I.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2021
Materias:	Review
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7827749/ https://www.ncbi.nlm.nih.gov/pubmed/33435257 http://dx.doi.org/10.3390/molecules26020328

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