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Reduction of the Diazo Functionality of α-Diazocarbonyl Compounds into a Methylene Group by NH(3)BH(3) or NaBH(4) Catalyzed by Au Nanoparticles
Supported Au nanoparticles on TiO(2) (1 mol%) are capable of catalyzing the reduction of the carbene-like diazo functionality of α-diazocarbonyl compounds into a methylene group [C=(N(2)) → CH(2)] by NH(3)BH(3) or NaBH(4) in methanol as solvent. The Au-catalyzed reduction that occurs within a few mi...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7832297/ https://www.ncbi.nlm.nih.gov/pubmed/33477732 http://dx.doi.org/10.3390/nano11010248 |