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Group 6 Hexacarbonyls as Ligands for the Silver Cation: Syntheses, Characterization, and Analysis of the Bonding Compared with the Isoelectronic Group 5 Hexacarbonylates

The syntheses of the two novel complexes [Ag{Mo/W(CO)(6)}(2)](+)[F‐{Al(OR(F))(3)}(2)](−) (R(F)=C(CF(3))(3)) are reported along with their structural and spectroscopic characterization. The X‐ray structure shows that three carbonyl ligands from each M(CO)(6) fragment bend towards the silver atom with...

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Detalles Bibliográficos
Autores principales: Bohnenberger, Jan, Kratzert, Daniel, Gorantla, Sai Manoj N. V. T., Pan, Sudip, Frenking, Gernot, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839444/
https://www.ncbi.nlm.nih.gov/pubmed/32964504
http://dx.doi.org/10.1002/chem.202003934