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Group 6 Hexacarbonyls as Ligands for the Silver Cation: Syntheses, Characterization, and Analysis of the Bonding Compared with the Isoelectronic Group 5 Hexacarbonylates
The syntheses of the two novel complexes [Ag{Mo/W(CO)(6)}(2)](+)[F‐{Al(OR(F))(3)}(2)](−) (R(F)=C(CF(3))(3)) are reported along with their structural and spectroscopic characterization. The X‐ray structure shows that three carbonyl ligands from each M(CO)(6) fragment bend towards the silver atom with...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839444/ https://www.ncbi.nlm.nih.gov/pubmed/32964504 http://dx.doi.org/10.1002/chem.202003934 |