The “Hidden” Reductive [2+2+1]‐Cycloaddition Chemistry of 2‐Phosphaethynolate Revealed by Reduction of a Th‐OCP Linkage

The reduction chemistry of the newly emerging 2‐phosphaethynolate (OCP)(−) is not well explored, and many unanswered questions remain about this ligand in this context. We report that reduction of [Th(Tren(TIPS))(OCP)] (2, Tren(TIPS)=[N(CH(2)CH(2)NSiPr(i) (3))](3−)), with RbC(8) via [2+2+1] cycloadd...

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Detalles Bibliográficos
Autores principales: Du, Jingzhen, Balázs, Gábor, Wooles, Ashley J., Scheer, Manfred, Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839465/
https://www.ncbi.nlm.nih.gov/pubmed/33051949
http://dx.doi.org/10.1002/anie.202012506

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839465/
https://www.ncbi.nlm.nih.gov/pubmed/33051949
http://dx.doi.org/10.1002/anie.202012506

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