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A Straightforward Synthesis of Polyketides via Ester Dienolate Matteson Homologation
Application of ester dienolates as nucleophiles in Matteson homologations allows for the stereoselective synthesis of highly substituted α,β‐unsaturated δ‐hydroxy carboxyl acids, structural motifs widespread found in polyketide natural products. The protocol is rather flexible and permits the introd...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839490/ https://www.ncbi.nlm.nih.gov/pubmed/33089903 http://dx.doi.org/10.1002/chem.202004650 |