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Catalytic, Kinetic, and Mechanistic Insights into the Fixation of CO(2) with Epoxides Catalyzed by Phenol‐Functionalized Phosphonium Salts

A series of hydroxy‐functionalized phosphonium salts were studied as bifunctional catalysts for the conversion of CO(2) with epoxides under mild and solvent‐free conditions. The reaction in the presence of a phenol‐based phosphonium iodide proceeded via a first order rection kinetic with respect to...

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Detalles Bibliográficos
Autores principales: Hu, Yuya, Wei, Zhihong, Frey, Anna, Kubis, Christoph, Ren, Chang‐Yue, Spannenberg, Anke, Jiao, Haijun, Werner, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839512/
https://www.ncbi.nlm.nih.gov/pubmed/33068328
http://dx.doi.org/10.1002/cssc.202002267