Use of Crown Ether Functions as Secondary Coordination Spheres for the Manipulation of Ligand–Metal Intramolecular Electron Transfer in Copper–Guanidine Complexes

Intramolecular electron transfer (IET) between a redox‐active organic ligand and a metal in a complex is of fundamental interest and used in a variety of applications. In this work it is demonstrated that secondary coordination sphere motifs can be applied to trigger a radical change in the electron...

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Detalles Bibliográficos
Autores principales: Haaf, Sebastian, Kaifer, Elisabeth, Wadepohl, Hubert, Himmel, Hans‐Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839521/
https://www.ncbi.nlm.nih.gov/pubmed/32833269
http://dx.doi.org/10.1002/chem.202003469

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839521/
https://www.ncbi.nlm.nih.gov/pubmed/32833269
http://dx.doi.org/10.1002/chem.202003469

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