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Electrochemical B−H Nitrogenation: Access to Amino Acid and BODIPY‐Labeled nido‐Carboranes

Electrocatalyzed oxidative B−H nitrogenations of nido‐carborane (nido‐7,8‐C(2)B(9)H(12) (−)) with N‐heterocycles have been established, enabling the preparation of various N‐substituted nido‐carboranes without chemical oxidants or metal catalyst under ambient conditions. The electrolysis manifold oc...

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Detalles Bibliográficos
Autores principales: Yang, Long, Bongsuiru Jei, Becky, Scheremetjew, Alexej, Kuniyil, Rositha, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839532/
https://www.ncbi.nlm.nih.gov/pubmed/32991021
http://dx.doi.org/10.1002/anie.202012105