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Cationic Functionalisation by Phosphenium Ion Insertion
The reaction of [Cp′′′Ni(η(3)‐P(3))] (1) with in situ generated phosphenium ions [RR′P](+) yields the unprecedented polyphosphorus cations of the type [Cp′′′Ni(η(3)‐P(4)R(2))][X] (R=Ph (2 a), Mes (2 b), Cy (2 c), 2,2′‐biphen (2 d), Me (2 e); [X](−)=[OTf](−), [SbF(6)](−), [GaCl(4)](−), [BAr(F)](−), [...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839539/ https://www.ncbi.nlm.nih.gov/pubmed/32996637 http://dx.doi.org/10.1002/chem.202003291 |