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Cationic Group VI Metal Imido Alkylidene N‐Heterocyclic Carbene Nitrile Complexes: Bench‐Stable, Functional‐Group‐Tolerant Olefin Metathesis Catalysts

Despite their excellent selectivities and activities, Mo‐and W‐based catalysts for olefin metathesis have not gained the same widespread use as Ru‐based systems, mainly due to their inherent air sensitivity. Herein, we describe the synthesis of air‐stable cationic‐at‐metal molybdenum and tungsten im...

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Detalles Bibliográficos
Autores principales: Benedikter, Mathis J., Musso, Janis V., Frey, Wolfgang, Schowner, Roman, Buchmeiser, Michael R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839548/
https://www.ncbi.nlm.nih.gov/pubmed/33009884
http://dx.doi.org/10.1002/anie.202011666