Isomerization Reactions in Anionic Mesoionic Carbene‐Borates and Control of Properties and Reactivities in the Resulting Co(II) Complexes through Agostic Interactions

We present herein anionic borate‐based bi‐mesoionic carbene compounds of the 1,2,3‐triazol‐4‐ylidene type that undergo C−N isomerization reactions. The isomerized compounds are excellent ligands for Co(II) centers. Strong agostic interactions with the “C−H”‐groups of the cyclohexyl substituents resu...

Descripción completa

Detalles Bibliográficos
Autores principales: Stubbe, Jessica, Neuman, Nicolás I., McLellan, Ross, Sommer, Michael G., Nößler, Maite, Beerhues, Julia, Mulvey, Robert E., Sarkar, Biprajit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839553/
https://www.ncbi.nlm.nih.gov/pubmed/33080102
http://dx.doi.org/10.1002/anie.202013376

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839553/
https://www.ncbi.nlm.nih.gov/pubmed/33080102
http://dx.doi.org/10.1002/anie.202013376

Ejemplares similares