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Insights into the Composition and Structural Chemistry of Gallium(I) Triflate

“GaOTf” is a simple, convenient source of low‐valent gallium for synthetic chemistry and catalysis. However, little is currently known about its composition or reactivity. In this work, (71)Ga NMR spectroscopy shows the presence of [Ga(arene)(n)](+) salts on oxidation of Ga metal with AgOTf in arene...

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Detalles Bibliográficos
Autores principales: Boronski, Josef T., Stevens, Matthew P., van IJzendoorn, Bono, Whitwood, Adrian C., Slattery, John M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839670/
https://www.ncbi.nlm.nih.gov/pubmed/33022877
http://dx.doi.org/10.1002/anie.202010837