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Quinoline Photobasicity: Investigation within Water‐Soluble Light‐Responsive Copolymers

Quinoline photobases exhibit a distinctly higher pK (a) in their electronically excited state than in the ground state, thereby enabling light‐controlled proton transfer reactions, for example, in molecular catalysis. The absorption of UV light translates to a pK (a) jump of approximately 10 units,...

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Detalles Bibliográficos
Autores principales: Sittig, Maria, Tom, Jessica C., Elter, Johanna K., Schacher, Felix H., Dietzek, Benjamin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839697/
https://www.ncbi.nlm.nih.gov/pubmed/32986286
http://dx.doi.org/10.1002/chem.202003815