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Chalcogen‐Transfer Rearrangement: Exploring Inter‐ versus Intramolecular P−P Bond Activation

tert‐Butyl‐substituted diphospha[2]ferrocenophane has been used as a stereochemically confined diphosphane to explore the addition of O, S, Se and Te. Although the diphosphanylchalcogane has been obtained for tellurium, all other chalcogens give diphosphane monochalcogenides. The latter transform vi...

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Detalles Bibliográficos
Autores principales: Franz, Roman, Nasemann, Sina, Bruhn, Clemens, Kelemen, Zsolt, Pietschnig, Rudolf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839705/
https://www.ncbi.nlm.nih.gov/pubmed/32678960
http://dx.doi.org/10.1002/chem.202002481