Azadiphosphaindane‐1,3‐diyls: A Class of Resonance‐Stabilized Biradicals

Conversion of 1,2‐bis(dichlorophosphino)benzene with sterically demanding primary amines led to the formation of 1,3‐dichloro‐2‐aza‐1,3‐diphosphaindanes of the type C(6)H(4)(μ‐PCl)(2)N‐R. Reduction yielded the corresponding 2‐aza‐1,3‐diphosphaindane‐1,3‐diyls (1), which can be described as phosphoru...

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Detalles Bibliográficos
Autores principales: Bresien, Jonas, Michalik, Dirk, Schulz, Axel, Villinger, Alexander, Zander, Edgar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839750/
https://www.ncbi.nlm.nih.gov/pubmed/33038288
http://dx.doi.org/10.1002/anie.202011886

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839750/
https://www.ncbi.nlm.nih.gov/pubmed/33038288
http://dx.doi.org/10.1002/anie.202011886

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