Cargando…
Azadiphosphaindane‐1,3‐diyls: A Class of Resonance‐Stabilized Biradicals
Conversion of 1,2‐bis(dichlorophosphino)benzene with sterically demanding primary amines led to the formation of 1,3‐dichloro‐2‐aza‐1,3‐diphosphaindanes of the type C(6)H(4)(μ‐PCl)(2)N‐R. Reduction yielded the corresponding 2‐aza‐1,3‐diphosphaindane‐1,3‐diyls (1), which can be described as phosphoru...
Autores principales: | Bresien, Jonas, Michalik, Dirk, Schulz, Axel, Villinger, Alexander, Zander, Edgar |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7839750/ https://www.ncbi.nlm.nih.gov/pubmed/33038288 http://dx.doi.org/10.1002/anie.202011886 |
Ejemplares similares
-
Rational
Design of Persistent Phosphorus-Centered
Singlet Tetraradicals and Their Use in Small-Molecule Activation
por: Zander, Edgar, et al.
Publicado: (2023) -
A Lewis Acid Stabilized Ketenimine in an Unusual Variant of the Electrophilic Aromatic Substitution
por: Surkau, Jonas, et al.
Publicado: (2022) -
Radical Reactivity of the Biradical [⋅P(μ‐NTer)(2)P⋅] and Isolation of a Persistent Phosphorus‐Cantered Monoradical [⋅P(μ‐NTer)(2)P‐Et]
por: Rosenboom, Jan, et al.
Publicado: (2022) -
A Phosphorus‐Based Pacman Dication Generated by Cooperative Self‐Activation of a Pacman Phosphane
por: Eickhoff, Liesa, et al.
Publicado: (2021) -
A chemical reaction controlled by light-activated molecular switches based on hetero-cyclopentanediyls
por: Bresien, Jonas, et al.
Publicado: (2019)