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Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic dienes

The Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic 1,3-dienes was investigated. A series of novel monofluorinated norbornenes was prepared in up to 97% yield. The reaction with 1,3-cyclohexadiene permits the preparation of monofluorinated bicyclo[2.2.2]oct-2-enes. The kinetic data of t...

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Detalles Bibliográficos
Autores principales: Ponomarev, Savva A, Larkovich, Roman V, Aldoshin, Alexander S, Tabolin, Andrey A, Ioffe, Sema L, Groß, Jonathan, Opatz, Till, Nenajdenko, Valentine G
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7849230/
https://www.ncbi.nlm.nih.gov/pubmed/33564337
http://dx.doi.org/10.3762/bjoc.17.27