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CF(3)-substituted carbocations: underexploited intermediates with great potential in modern synthetic chemistry

“The extraordinary instability of such an “ion” accounts for many of the peculiarities of organic reactions” – Franck C. Whitmore (1932). This statement from Whitmore came in a period where carbocations began to be considered as intermediates in reactions. Ninety years later, pointing at the strong...

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Detalles Bibliográficos
Autores principales: Fernandes, Anthony J, Panossian, Armen, Michelet, Bastien, Martin-Mingot, Agnès, Leroux, Frédéric R, Thibaudeau, Sébastien
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7871035/
https://www.ncbi.nlm.nih.gov/pubmed/33828616
http://dx.doi.org/10.3762/bjoc.17.32