Cargando…
CF(3)-substituted carbocations: underexploited intermediates with great potential in modern synthetic chemistry
“The extraordinary instability of such an “ion” accounts for many of the peculiarities of organic reactions” – Franck C. Whitmore (1932). This statement from Whitmore came in a period where carbocations began to be considered as intermediates in reactions. Ninety years later, pointing at the strong...
Autores principales: | Fernandes, Anthony J, Panossian, Armen, Michelet, Bastien, Martin-Mingot, Agnès, Leroux, Frédéric R, Thibaudeau, Sébastien |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7871035/ https://www.ncbi.nlm.nih.gov/pubmed/33828616 http://dx.doi.org/10.3762/bjoc.17.32 |
Ejemplares similares
-
Formation of synthetically relevant CF(3)-substituted phenonium ions in superacid media
por: Fernandes, Anthony J., et al.
Publicado: (2021) -
Recent developments in carbocation and onium ion chemistry
por: Laali, Kenneth K
Publicado: (2007) -
Transient and intermediate carbocations in ruthenium tetroxide oxidation of saturated rings
por: Pedrón, Manuel, et al.
Publicado: (2019) -
β-Hydroxy carbocation intermediates in solvolyses of di- and tetra-hydronaphthalene substrates
por: Kudavalli, Jaya S, et al.
Publicado: (2010) -
Inherent atomic mobility changes in carbocation intermediates during the sesterterpene cyclization cascade
por: Sato, Hajime, et al.
Publicado: (2019)