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Cluster Salts [Nb(6)Cl(12)(HIm)(6)]A(n) (with HIm=1H‐imidazole and A=Mineral Acid Anion, n=1 or 2) Made in and with Brønsted‐basic Ionic Liquids and Liquid Mixtures

Four new hexanuclear niobium cluster compounds of the general formula [Nb(6)Cl(12)(HIm)(6)](A)(n) ⋅ x(solvent molecule) (HIm=1H‐imidazole, A=mineral acid anion, Cl(−) (n=2) (1), (SO(4))(2−) (n=1) (2), (CrO(4))(2−) (n=1) (3), and (HAsO(4))(2−) (n=1) (4)) were prepared. Their synthesis can be done in...

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Detalles Bibliográficos
Autores principales: Sperlich, Eric, Köckerling, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7874250/
https://www.ncbi.nlm.nih.gov/pubmed/33534197
http://dx.doi.org/10.1002/open.202000266