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Metal Assisted Synthesis of Cationic Sulfidobismuth Cubanes in Ionic Liquids

Bi(2)S(3) was dissolved in the presence of either AuCl/PtCl(2) or AgCl in the ionic liquids [BMIm]Cl ⋅ xAlCl(3) (BMIm=1‐n‐butyl‐3‐methylimidazolium; x=4–4.3) through annealing the mixtures at 180 or 200 °C. Upon cooling to room temperature, orange, air‐sensitive crystals of [BMIm](Bi(4)S(4))[AlCl(4)...

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Detalles Bibliográficos
Autores principales: Knies, Maximilian, Groh, Matthias F., Pietsch, Tobias, Lê Anh, Mai, Ruck, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7874255/
https://www.ncbi.nlm.nih.gov/pubmed/33565736
http://dx.doi.org/10.1002/open.202000246