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Schiff Base Cobalt(II) Complex-Catalyzed Highly Markovnikov-Selective Hydrosilylation of Alkynes

[Image: see text] A bench-stable cobalt(II) complex, with 3N-donor socket-type benzimidazole-imine-2H-imidazole ligand is reported as a precatalyst for regioselective hydrosilylation of terminal alkynes. Both aromatic and aliphatic alkynes could be effectively hydrosilylated with primary, secondary,...

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Detalles Bibliográficos
Autores principales: Skrodzki, Maciej, Patroniak, Violetta, Pawluć, Piotr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7875507/
https://www.ncbi.nlm.nih.gov/pubmed/33439031
http://dx.doi.org/10.1021/acs.orglett.0c03721