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Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group

The development of straightforward synthesis of regio- and stereodefined alkenes with multiple aliphatic substituents under mild conditions is an unmet challenge owing to competitive β-hydride elimination and selectivity issues. Herein, we report the nickel-catalyzed intermolecular cross-dialkylatio...

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Detalles Bibliográficos
Autores principales: Zhan, Yi-Zhou, Xiao, Nan, Shu, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7876002/
https://www.ncbi.nlm.nih.gov/pubmed/33568646
http://dx.doi.org/10.1038/s41467-021-21083-w