Aryl C(sp(2))–X Coupling (X = C, N, O, Cl) and Facile Control of N-Mono- and N,N-Diarylation of Primary Alkylamines at a Pt(IV) Center

[Image: see text] We present the first example of an unprecedented and fast aryl C(sp(2))–X reductive elimination from a series of isolated Pt(IV) aryl complexes (Ar = p-FC(6)H(4)) LPt(IV)F(py)(Ar)X (X = CN, Cl, 4-OC(6)H(4)NO(2)) and LPt(IV)F(2)(Ar)(HX) (X = NHAlk; Alk = n-Bu, PhCH(2), cyclo-C(6)H(1...

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Detalles Bibliográficos
Autores principales: Lin, Xiaoxi, Vigalok, Arkadi, Vedernikov, Andrei N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7884019/
https://www.ncbi.nlm.nih.gov/pubmed/33226792
http://dx.doi.org/10.1021/jacs.0c09452

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7884019/
https://www.ncbi.nlm.nih.gov/pubmed/33226792
http://dx.doi.org/10.1021/jacs.0c09452

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