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Aryl C(sp(2))–X Coupling (X = C, N, O, Cl) and Facile Control of N-Mono- and N,N-Diarylation of Primary Alkylamines at a Pt(IV) Center
[Image: see text] We present the first example of an unprecedented and fast aryl C(sp(2))–X reductive elimination from a series of isolated Pt(IV) aryl complexes (Ar = p-FC(6)H(4)) LPt(IV)F(py)(Ar)X (X = CN, Cl, 4-OC(6)H(4)NO(2)) and LPt(IV)F(2)(Ar)(HX) (X = NHAlk; Alk = n-Bu, PhCH(2), cyclo-C(6)H(1...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7884019/ https://www.ncbi.nlm.nih.gov/pubmed/33226792 http://dx.doi.org/10.1021/jacs.0c09452 |