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The Impact of Water on Ru-Catalyzed Olefin Metathesis: Potent Deactivating Effects Even at Low Water Concentrations

[Image: see text] Ruthenium catalysts for olefin metathesis are widely viewed as water-tolerant. Evidence is presented, however, that even low concentrations of water cause catalyst decomposition, severely degrading yields. Of 11 catalysts studied, fast-initiating examples (e.g., the Grela catalyst...

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Detalles Bibliográficos
Autores principales: Blanco, Christian O., Sims, Joshua, Nascimento, Daniel L., Goudreault, Alexandre Y., Steinmann, Stephan N., Michel, Carine, Fogg, Deryn E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7886052/
https://www.ncbi.nlm.nih.gov/pubmed/33614193
http://dx.doi.org/10.1021/acscatal.0c04279