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The Impact of Water on Ru-Catalyzed Olefin Metathesis: Potent Deactivating Effects Even at Low Water Concentrations
[Image: see text] Ruthenium catalysts for olefin metathesis are widely viewed as water-tolerant. Evidence is presented, however, that even low concentrations of water cause catalyst decomposition, severely degrading yields. Of 11 catalysts studied, fast-initiating examples (e.g., the Grela catalyst...
Autores principales: | Blanco, Christian O., Sims, Joshua, Nascimento, Daniel L., Goudreault, Alexandre Y., Steinmann, Stephan N., Michel, Carine, Fogg, Deryn E. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7886052/ https://www.ncbi.nlm.nih.gov/pubmed/33614193 http://dx.doi.org/10.1021/acscatal.0c04279 |
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