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Visible‐Light‐Mediated Heterocycle Functionalization via Geometrically Interrupted [2+2] Cycloaddition

The [2+2] photocycloaddition is the most valuable and intensively investigated photochemical process. Here we demonstrate that irradiation of N‐acryloyl heterocycles with blue LED light (440 nm) in the presence of an Ir(III) complex leads to efficient and high yielding fused γ‐lactam formation acros...

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Detalles Bibliográficos
Autores principales: Popescu, Mihai V., Mekereeya, Aroonroj, Alegre‐Requena, Juan V., Paton, Robert S., Smith, Martin D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7891567/
https://www.ncbi.nlm.nih.gov/pubmed/32856748
http://dx.doi.org/10.1002/anie.202009704