Ligand Protonation Triggers H(2) Release from a Dinickel Dihydride Complex to Give a Doubly “T”‐Shaped Dinickel(I) Metallodiradical

The dinickel(II) dihydride complex (1(K)) of a pyrazolate‐based compartmental ligand with β‐diketiminato (nacnac) chelate arms (L(−)), providing two pincer‐type {N(3)} binding pockets, has been reported to readily eliminate H(2) and to serve as a masked dinickel(I) species. Discrete dinickel(I) comp...

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Detalles Bibliográficos
Autores principales: Duan, Peng‐Cheng, Schulz, Roland Alexander, Römer, Anton, Van Kuiken, Benjamin E., Dechert, Sebastian, Demeshko, Serhiy, Cutsail, George E., DeBeer, Serena, Mata, Ricardo A., Meyer, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7894169/
https://www.ncbi.nlm.nih.gov/pubmed/33026170
http://dx.doi.org/10.1002/anie.202011494

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7894169/
https://www.ncbi.nlm.nih.gov/pubmed/33026170
http://dx.doi.org/10.1002/anie.202011494

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