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Urea‐Substituted Tetramethylcyclopentadienyl Ligands for Supramolecularly Accelerated Rh(III)‐Catalyzed ortho‐C−H Olefination of Benzoic Acid Derivatives
The design and synthesis of air‐stable and conveniently crystallizable Rh(III)‐cyclopentadienyl catalysts substituted with a urea moiety, which are able to accelerate the C−H olefination of benzoic acid derivatives, is reported. Through kinetic studies and NMR titration experiments, the catalysts’ s...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898290/ https://www.ncbi.nlm.nih.gov/pubmed/33294985 http://dx.doi.org/10.1002/chem.202005130 |