Nickel‐Catalyzed Intramolecular 1,2‐Aryl Migration of Mesoionic Carbenes (iMICs)

Intramolecular 1,2‐Dipp migration of seven mesoionic carbenes (iMIC(Ar)) 2 a–g (iMIC(Ar)=ArC{N(Dipp)}(2)CHC; Ar=aryl; Dipp=2,6‐iPr(2)C(6)H(3)) under nickel catalysis to give 1,3‐imidazoles (IMD(Ar)) 3 a–g (IMD(Ar)=ArC{N(Dipp)CHC(Dipp)N}) has been reported. The formation of 3 indicates the cleavage o...

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Detalles Bibliográficos
Autores principales: Merschel, Arne, Glodde, Timo, Neumann, Beate, Stammler, Hans‐Georg, Ghadwal, Rajendra S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898293/
https://www.ncbi.nlm.nih.gov/pubmed/33155756
http://dx.doi.org/10.1002/anie.202014328

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898293/
https://www.ncbi.nlm.nih.gov/pubmed/33155756
http://dx.doi.org/10.1002/anie.202014328

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