Calcium Hydride Catalysts for Olefin Hydrofunctionalization: Ring‐Size Effect of Macrocyclic Ligands on Activity

The fifteen‐membered NNNNN macrocycle Me(5)PACP (Me(5)PACP=1,4,7,10,13‐pentamethyl‐1,4,7,10,13‐pentaazacyclopentadecane) stabilized the [CaH](+) fragment as a dimer with a distorted pentagonal bipyramidal coordination geometry at calcium. The hydride complex was prepared by protonolysis of calcium d...

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Detalles Bibliográficos
Autores principales: Höllerhage, Thomas, Schuhknecht, Danny, Mistry, Alisha, Spaniol, Thomas P., Yang, Yan, Maron, Laurent, Okuda, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898310/
https://www.ncbi.nlm.nih.gov/pubmed/33185286
http://dx.doi.org/10.1002/chem.202004931

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898310/
https://www.ncbi.nlm.nih.gov/pubmed/33185286
http://dx.doi.org/10.1002/chem.202004931

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