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Spin‐Controlled Binding of Carbon Dioxide by an Iron Center: Insights from Ultrafast Mid‐Infrared Spectroscopy
The influence of the spin on the mode of binding between carbon dioxide (CO(2)) and a transition‐metal (TM) center is an entirely open question. Herein, we use an iron(III) oxalato complex with nearly vanishing doublet–sextet gap, and its ultrafast photolysis, to generate TM‐CO(2) bonding patterns a...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898313/ https://www.ncbi.nlm.nih.gov/pubmed/33022879 http://dx.doi.org/10.1002/anie.202012739 |