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From π‐Bonded Gallapnictenes to Nucleophilic, Redox‐Active Metal‐Coordinated Pnictanides
A comprehensive reactivity study of gallapnictenes LGaEGa(Cl)L (E=As, Sb; L=HC[C(Me)N(Ar)](2), Ar=Dip=2,6‐i‐Pr(2)C(6)H(3)) proved the nucleophilic character of the pnictogen and the electrophilic nature of the Ga atom. Reactions of LGaEGa(Cl)L with imidazolium chloride [IPrH][Cl] yielded {[LGa(Cl)](...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898314/ https://www.ncbi.nlm.nih.gov/pubmed/33200865 http://dx.doi.org/10.1002/anie.202013618 |