Activation of Molecular Oxygen by a Cobalt(II) Tetra‐NHC Complex

The first dicobalt(III) μ (2)‐peroxo N‐heterocyclic carbene (NHC) complex is reported. It can be quantitatively generated from a cobalt(II) compound bearing a 16‐membered macrocyclic tetra‐NHC ligand via facile activation of dioxygen from air at ambient conditions. The reaction proceeds via an end‐o...

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Detalles Bibliográficos
Autores principales: Schlagintweit, Jonas F., Altmann, Philipp J., Böth, Alexander D., Hofmann, Benjamin J., Jandl, Christian, Kaußler, Clemens, Nguyen, Linda, Reich, Robert M., Pöthig, Alexander, Kühn, Fritz E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898330/
https://www.ncbi.nlm.nih.gov/pubmed/33125815
http://dx.doi.org/10.1002/chem.202004758

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898330/
https://www.ncbi.nlm.nih.gov/pubmed/33125815
http://dx.doi.org/10.1002/chem.202004758

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