Reversible Activation and Transfer of White Phosphorus by Silyl‐Stannylene

Use of a silyl supported stannylene ((Mes)TerSn(Si(t)Bu(3)) [(Mes)Ter=2,6‐(2,4,6‐Me(3)C(6)H(2))(2)C(6)H(3)] enables activation of white phosphorus under mild conditions, which is reversible under UV light. The reaction of a silylene chloride with the activated P(4) complex results in facile P‐atom t...

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Detalles Bibliográficos
Autores principales: Sarkar, Debotra, Weetman, Catherine, Munz, Dominik, Inoue, Shigeyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898380/
https://www.ncbi.nlm.nih.gov/pubmed/33155395
http://dx.doi.org/10.1002/anie.202013423

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898380/
https://www.ncbi.nlm.nih.gov/pubmed/33155395
http://dx.doi.org/10.1002/anie.202013423

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