Reversible Activation and Transfer of White Phosphorus by Silyl‐Stannylene

Use of a silyl supported stannylene ((Mes)TerSn(Si(t)Bu(3)) [(Mes)Ter=2,6‐(2,4,6‐Me(3)C(6)H(2))(2)C(6)H(3)] enables activation of white phosphorus under mild conditions, which is reversible under UV light. The reaction of a silylene chloride with the activated P(4) complex results in facile P‐atom t...

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Detalles Bibliográficos
Autores principales: Sarkar, Debotra, Weetman, Catherine, Munz, Dominik, Inoue, Shigeyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898380/
https://www.ncbi.nlm.nih.gov/pubmed/33155395
http://dx.doi.org/10.1002/anie.202013423
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author Sarkar, Debotra
Weetman, Catherine
Munz, Dominik
Inoue, Shigeyoshi
author_facet Sarkar, Debotra
Weetman, Catherine
Munz, Dominik
Inoue, Shigeyoshi
author_sort Sarkar, Debotra
collection PubMed
description Use of a silyl supported stannylene ((Mes)TerSn(Si(t)Bu(3)) [(Mes)Ter=2,6‐(2,4,6‐Me(3)C(6)H(2))(2)C(6)H(3)] enables activation of white phosphorus under mild conditions, which is reversible under UV light. The reaction of a silylene chloride with the activated P(4) complex results in facile P‐atom transfer. The computational analysis rationalizes the electronic features and high reactivity of the heteroleptic silyl‐substituted stannylene in contrast to the previously reported bis(aryl)stannylene.
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spelling pubmed-78983802021-03-03 Reversible Activation and Transfer of White Phosphorus by Silyl‐Stannylene Sarkar, Debotra Weetman, Catherine Munz, Dominik Inoue, Shigeyoshi Angew Chem Int Ed Engl Communications Use of a silyl supported stannylene ((Mes)TerSn(Si(t)Bu(3)) [(Mes)Ter=2,6‐(2,4,6‐Me(3)C(6)H(2))(2)C(6)H(3)] enables activation of white phosphorus under mild conditions, which is reversible under UV light. The reaction of a silylene chloride with the activated P(4) complex results in facile P‐atom transfer. The computational analysis rationalizes the electronic features and high reactivity of the heteroleptic silyl‐substituted stannylene in contrast to the previously reported bis(aryl)stannylene. John Wiley and Sons Inc. 2020-12-21 2021-02-15 /pmc/articles/PMC7898380/ /pubmed/33155395 http://dx.doi.org/10.1002/anie.202013423 Text en © 2020 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Sarkar, Debotra
Weetman, Catherine
Munz, Dominik
Inoue, Shigeyoshi
Reversible Activation and Transfer of White Phosphorus by Silyl‐Stannylene
title Reversible Activation and Transfer of White Phosphorus by Silyl‐Stannylene
title_full Reversible Activation and Transfer of White Phosphorus by Silyl‐Stannylene
title_fullStr Reversible Activation and Transfer of White Phosphorus by Silyl‐Stannylene
title_full_unstemmed Reversible Activation and Transfer of White Phosphorus by Silyl‐Stannylene
title_short Reversible Activation and Transfer of White Phosphorus by Silyl‐Stannylene
title_sort reversible activation and transfer of white phosphorus by silyl‐stannylene
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898380/
https://www.ncbi.nlm.nih.gov/pubmed/33155395
http://dx.doi.org/10.1002/anie.202013423
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